CoreChem:SI Prefixes

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{reg}1.3.2 SI Prefixes

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Introduction (Original)

Atoms, Molecules and Chemical Reactions (Original)















16.1 Spontaneous Processes and Molecular Probability

16.2 Thermodynamic Probability and Entropy

16.3 Getting Acquainted with Entropy

16.4 Including the Surroundings

16.5 The Free Energy

16.6 Equilibrium Constants Revisited

Summary 16


17.1 Electrolysis

17.2 Commercial Applications of Electrolysis

17.3 Quantitative Aspects of Electrolysis

17.4 Galvanic Cells

17.5 Electromotive Force of Galvanic Cells

17.6 Commercial Galvanic Cells

17.7 Galvanic Cells and Free Energy

Summary 17


18.1 Experimental Measurement of Rates

18.2 Microscopic View of Chemical Reactions

18.3 Reaction Mechanisms

18.4 Increasing the Rate of a Reaction

18.5 Some Important Types of Catalysts

Summary 18


19.1 Naturally Occurring Nuclear Reactions

19.2 Artificially Induced Nuclear Reactions

19.3 Nuclear Stability

19.4 The Rate of Radioactive Decay

19.5 Detection and Measurement of Radiation

19.6 Uses of Artificial Isotopes in Chemistry

19.7 Mass-Energy Relationships

19.8 Nuclear Fission

19.9 Nuclear Fusion

Summary 19


20.1 The Elements of Life

20.2 The Building Blocks of Biochemistry

20.3 Fats and Lipids

20.4 Carbohydrates

20.5 Proteins

20.6 Nucleic Acids

Summary 20


21.1 The Nature of Electromagnetic Radiation

21.2 Atomic Spectra and the Bohr Theory

21.3 The Spectra of Molecules: Infrared

21.4 The Visible and Ultraviolet Spectra of Molecules: Molecular Orbitals

Summary 21


22.1 Metallic Bonding

22.2 Metallurgy

22.3 Coordination Compounds

22.4 Transitional Metal Ions in Aqueous Solutions

Summary 22

{/reg} The SI base units are not always of convenient size for a particular measurement. For example, the meter would be too big for reporting the thickness of this page, but rather small for the distance from Chicago to Detroit. To overcome this obstacle the SI includes a series of prefixes, each of which represents a power of 10 (Table 1.3). These allow us to reduce or enlarge the SI base units to convenient sizes. Figure 1.5 shows how these prefixes can be applied to the meter to cover almost the entire range of lengths we might wish to measure.


TABLE 1.3 Prefixes Used for Decimal Fractions and Multiples of SI Units.

Image:Chapter_one_page_18.jpg

One non-SI unit of length, the angstrom (Å), is convenient for chemists and will continue to be used for a limited time. Since 1Å = 10–10 m (see Fig. 1.5), the angstrom corresponds roughly to the diameters of atoms and small molecules. Such dimensions are also conveniently expressed in picometers, 1 pm = 10–12 m = 0.01Å, but the angstrom is widely used and very familiar. Therefore we will usually write atomic and molecular dimensions in both angstroms and picometers.

The SI base unit of mass, the kilogram, is unusual because it already contains a prefix. The standard kilogram is a cylinder of corrosion-resistant platinum-iridium alloy which is kept at the International Bureau of Weights and Measures near Paris. The kilogram was chosen instead of a gram because the latter would have made an inconveniently small piece of platinum-iridium and would have been difficult to handle. Also, units of force, pressure, energy, and power have been derived using the kilogram instead of the gram.

Figure 1.5 The magnitudes of some distances and lengths in the range 1018 through 10–18 m, expressed in SI units.
Figure 1.5 The magnitudes of some distances and lengths in the range 1018 through 10–18 m, expressed in SI units.


Despite the fact that the kilogram is the SI unit of mass, the standard prefixes are applied to the gram when larger or smaller mass units are needed. For example, the quantity 106 kg (1 million kilograms) can be written as 1 Gg (gigagram) but not as 1 Mkg (megakilogram). The operative rule here is that one and only one prefix should be attached to the name for a unit. Figure 1.6 illustrates the use of this rule in expressing the wide range of masses available in the universe. Note that the masses of atoms and molecules are usually so small that scientific notation must be used instead of prefixes.

Figure 1.6 The masses of some objects in the range 1018 through 10–27 g, expressed in SI units.
Figure 1.6 The masses of some objects in the range 1018 through 10–27 g, expressed in SI units.